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Oxide solid electrolytes are attractive for the implementation of solid‐state Li‐ion batteries. However, constrained by the large ion‐transport hindrance inside the densely packed lattice, their Li‐ion conductivity can hardly reach the level of liquid electrolytes. A strategy of introducing confined water into the lattice paves a new way for enhancing the Li‐ion transport, which has been reported...
Li‐Ion Batteries
Developing new oxide solid electrolytes with fast Li‐ion transport and high stability is an important step to realize high‐performance solid‐state Li‐ion batteries. In article number 2201094, Tao Gao, Zilong Tang, and co‐workers discover that confined water in quaternary Li–H–Ti–O solid electrolytes can enhance ionic conductivity. Meanwhile, strong covalent bonds between confined...
Developing new oxide solid electrolytes with fast Li‐ion transport and high stability is an important step to realize high‐performance solid‐state Li‐ion batteries. Hydrate materials containing confined water widely exist in nature or can be easily synthesized. However, they have seldom been explored as Li‐ion solid electrolytes due to the stereotype that the presence of water limits the electrochemical...
Proton conduction underlies many important electrochemical technologies. A family of new proton electrolytes is reported: acid‐in‐clay electrolyte (AiCE) prepared by integrating fast proton carriers in a natural phyllosilicate clay network, which can be made into thin‐film (tens of micrometers) fluid‐impervious membranes. The chosen example systems (sepiolite–phosphoric acid) rank top among the solid...
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