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Erstmals wurden DNA‐Filme mit künstlichen Nucleobasen sequenzabhängig auf den Ladungstransferwiderstand (RCT) der metallmodifizierten DNA hin untersucht. Das Imidazol‐Desoxyribonucleosid (Im) wurde als hochgradig AgI‐spezifisches Ligandosid zur Bildung von Im‐AgI‐Im‐Komplexen innerhalb der Doppelhelices genutzt. Dieser neue Typ positionsspezifisch metallmodifizierter DNA‐Film wurde mit UV‐, Circulardichroismus‐...
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