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We describe a nanoscale gating effect by an atypical tether-containing polythiophene, [poly(thiophene-3-carboxylic acid 2-(2-(2-(2-ethoxy-ethoxymethyl sulfonate)-ethoxy)-ethoxy)-amide], referred to as poly(TP-OEG-SO 4 ). Cyclic voltammetry data permitted us to calculate liquid-phase ion diffusivities in the polymer as a function of its oxidation state. Diffusivities are more than 350 times...
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