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The oxidative dehydrogenation of propane on CuO has been investigated at 723 K in the presence and absence of tetrachloromethane (TCM). Under oxygen-limiting conditions, the conversion of propane and the selectivity to propylene were enhanced by the introduction of TCM. The catalyst converted to metallic Cu during the oxidation in the absence of TCM while no conversion of CuO was observed in the sample...
The oxidative dehydrogenation of propane to propylene has been investigated on α-magnesium pyrovanadate (Mg2V2O7) at 723 K in the presence and absence of tetrachloromethane (TCM). Under the present conditions, the conversion of propane and the selectivity to propylene were 5.0 and 74.5%, respectively, in the absence of TCM while those were 14.0 and 70.2%, respectively, upon addition of a small amount...
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