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Crystalline block copolymers tend to display a peculiar and intriguing behavior upon the external additives. In this work, we systematically investigated the self-assembly and crystallization behavior of polymethylene-b-poly (acrylic acid) crystalline diblock copolymer (PM-b-PAA, M93A94) in the presence of calcium chloride (CaCl2). When molar ratio between CaCl2 and constituent deprotonated carboxyl...
Amorphous poly(ethylene terephthalate) was annealed at temperatures around the glass transition temperature and then heated up in differential scanning calorimeter at 20 o Cmin -1 . It was found that the annealing favored the subsequent cold crystallization and this effect became stronger with increasing annealing temperature. The experimental results were explained by considering...
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