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Selective oxidation is of key importance in the synthesis of chemical intermediates. For many years a number of oxides and supported metal catalysts have been used. The key questions involved in the design of selective oxidation catalysts are discussed in the initial part of this paper. One of the most exciting recent developments in the field of selective oxidation has been the discovery that supported...
The direct synthesis of H 2 O 2 at low temperature (2 °C) from H 2 and O 2 using TiO 2 -supported Au, Pd, and Au–Pd catalysts is discussed. The Au–Pd catalysts performed significantly better than the pure Pd/TiO 2 and Au/TiO 2 materials. Au–Pd particles were found with a core–shell structure, with Pd concentrated on the surface. The highest yields...
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