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In this contribution the first examples of so‐called rigid‐core, T‐shaped imidazolium ionic liquid crystals, in which the C‐2 atom of the imidazolium ring is substituted with an aryl moiety decorated with one or two alkoxy chains, are described. The length of the alkoxy chain(s) was varied from six to eighteen carbon atoms (n=6, 10, 14–18). Whereas the compounds with one long alkoxy chain display...
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