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Seit der Isolierung des ersten freien N‐Heterocyclencarbens vor über 20 Jahren ist diese Ligandenklasse unverzichtbar in der modernen Chemie geworden. Diese Entwicklung basiert maßgeblich auf der Stabilität der Metall‐Kohlenstoff‐Bindung, der problemlosen Feinabstimmung der Ligandeneigenschaften, sowie dem leichten synthetischen Zugang zu derartigen Komplexen. Als Steuerliganden sind sie Bestandteil...
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