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A novel 3D NbO metal-organic framework, [Cd2(pam)2(bpt)2(H2O)]n·0.68nH2O (1) (H2pam=pamoic acid and bpt=2,5-bis(4-pyridyl)-1,3,4-thiadiazole), has been synthesized by the structural cooperation of well-chosen flexible aromatic acid and rigid bipyridyl ligand. The rare severely distorted mixed-ligand mesomeric networks accommodate two individual heterochiral frameworks interpenetrating with each other...
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