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Despite the widespread success in the functionalization of C(sp2)−H bonds, the deliberate functionalization of C(sp3)−H bonds in a highly site‐ and stereoselective manner remains a longstanding challenge. Herein, we report an iridium/aluminum cooperative catalytic system that enables the β‐selective C−H borylation of saturated cyclic amines and lactams. Furthermore, we have accomplished an enantioselective...
Despite the widespread success in the functionalization of C(sp2)−H bonds, the deliberate functionalization of C(sp3)−H bonds in a highly site‐ and stereoselective manner remains a longstanding challenge. Herein, we report an iridium/aluminum cooperative catalytic system that enables the β‐selective C−H borylation of saturated cyclic amines and lactams. Furthermore, we have accomplished an enantioselective...