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The expanded phthalocyanine (EPc) single‐layer sheets with embedded double transition metals (labeled as TM2EPc) are predicted to be a novel class of highly stable 2D materials with a series of fascinating properties by means of systematic first‐principles calculations, molecular dynamics, and Monte Carlo simulations. Excitingly, the ferromagnetic Cr2EPc and antiferromagnetic Mn2– and Fe2–EPc have...
The serious shuttle effect and sluggish reaction kinetics intrinsically handicap the practical application of Li‐S batteries. Herein, a unique 3D hierarchically porous Mott–Schottky electrocatalyst composed of W2C quantum dots (QD) spatially confined in nitrogen‐doped graphene microspheres (NGM) is proposed for regulating the kinetics of sulfur electrochemistry. Experimental and theoretical results...
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