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Tris(2,2,2-trifluoroethyl) phosphite (TTFEP) is investigated as an electrolyte additive to improve the electrochemical performance of LiNi1/3Co1/3Mn1/3O2 cathode at high operating voltage (4.6V). Charge/discharge measurements demonstrate that TTFEP is effective to improve the cycling stability and rate capability of LiNi1/3Co1/3Mn1/3O2 cathode. The capacity retention of LiNi1/3Co1/3Mn1/3O2/Li cell...
Triphenyl phosphite (TPPi) was investigated as an electrolyte additive for high-voltage lithium-ion batteries using lithium-rich layered oxide cathode in this paper. The cyclic stability of Li1.16Ni0.2Co0.1Mn0.54O2 was improved significantly with the adoption of 0.2wt. % TPPi. The capacity retention of Li1.16Ni0.2Co0.1Mn0.54O2 was improved significantly, especially at elevated temperature, from 69...
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