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Longibrachiamide A (1), a new 20‐residue peptaibol, along with three known ones (2–4), were isolated from the fungus Trichoderma longibrachiatum Rifai DMG‐3‐1‐1, isolated from a mushroom Clitocybe nebularis (Batsch) P. Kumm, which was collected from coniferous forest of northeast China in our previous work. The structure of longibrachiamide A (1) was determined by its NMR and ESI‐MS/MS data, the absolute...
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