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A Protein Data Bank (PDB) study was undertaken to investigate the role of C-X...π interactions (X=F, Cl, Br, I) in protein structures. From this analysis, it is evident that the propensity for the formation of C-X...π interactions is higher in case of fluorine than in other halogens. These results compare well with the recently reported C-X...π interactions in small molecules and depict the orientational...
A Cambridge Structural Database study was undertaken to investigate the role of C-X...π interactions (X=F, Cl, Br, I) in conformational and crystal engineering control in organic crystal structures. This analysis reveals that organic fluorine has a greater propensity for the formation of such interactions rather than accepting hydrogen bonds. These results also compare well with the recently analyzed...
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