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We present the first experimental spectroscopy and calorimetry proof of the existence of polymorphism in ortho-bromobenzophenone (2BrBP). The crystallization and melting processes of the two polymorphic phases were monitored by infrared spectroscopy. The crystallization of the metastable phase occurs in the supercooled region at 245K upon heating of the glassy 2BrBP. The metastable phase melts below...
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