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The reaction of 2-(2-aminophenyl)benzothiazole (Habt) with [Re(CO) 5 Br] led to the isolation of the rhenium(I) complex fac-[Re(Habt)(CO) 3 Br] (1). With trans-[ReOCl 3 (PPh 3 ) 2 ], the ligand Habt decomposed to form the oxofree rhenium(V) complex [Re(itp) 2 Cl(PPh 3 )] (2) (itp=2-amidophenylthiolate). From the reaction of trans-[ReOBr 3...
Three monocationic rhenium(I) complexes of the type [Re(CO) 3 (L)]Br, containing the bis-imidazole tridentate ligands bis-(2-(1-methylimidazolyl)methyl)amine (L 1 ), bis-(2-(1-methylimidazolyl)methyl)aminoethanol (L 2 ) and bis-(2-(benzimidazolyl)ethyl)sulfide (L 3 ), were prepared and characterized by 1 H NMR and IR spectroscopy. The complex salt [Re(CO) ...
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