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Electrochemical nitriding of a liquid phase tin metal has experimentally been confirmed by using the oxidation of nitride ions in molten LiCl–KCl–Li 3 N melts according to the following reactions:N3−=Nads+3e−Nads+Sn=SnNxFrom the XPS analysis, N 1s signal and Sn 3d signals are observed, which corresponds to the formation of SnN x , after conducting argon ion sputtering for 1000s. This...
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