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Transition metal catalyzed carbon—hydrogen functionalization imparts a paradigm shift in the complex target synthesis, including pharmaceutical and material science applications. To establish structure‐function‐property relationship of covalent organic frameworks, palladium docked dual‐pore COFs with controllable bipyridine content exhibit regioselective C—H to C—X (X = Cl, Br, I) and C—O functionalization,...
Exponential growth in the field of covalent–organic frameworks (COFs) is emanating from the direct correlation between designing principles and desired properties. The comparison of catalytic activity between single‐pore and dual‐pore COFs is of importance to establish structure–function relationship. Herein, the synthesis of imine‐linked dual‐pore [(BPyDC)]x%‐ETTA COFs (x = 0%, 25%, 50%, 75%, 100%)...
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