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Five models that account for experimental observations of kinetics and surface properties during trichloroethylene (TCE) transformation by iron were compared in terms of accuracy in fitting sixteen TCE concentration versus time profiles obtained from the literature. The models were based on Henri–Michaelis–Menten/Langmuir–Hinshelwood–Hougen–Watson (HMM/LHHW) kinetics and considered sorption to inactive...
The rate coefficients for the photosensitized oxidation of various phenols in aqueous solutions containing dissolved natural organic material increased in some cases with decreasing phenol concentration. For 3,4-dimethoxyphenol and 4-methoxyphenol at initial concentration going from 10 to 1.0 μM, the rate coefficients increased by a factor of 5 in a humic acid solution and by a factor of 2 in a fulvic...
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