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The reaction of AsPh 3 with Ni/Al 2 O 3 at 100 to 200°C under 6 to 30 bars of hydrogen has been followed by kinetic analysis of both the consumption of AsPh 3 and the evolution of benzene and cyclohexane as well as magnetic and XRD measurements of the metallic and intermetallic phase(s). The reaction proceeds via complete hydrogenolysis of the As–Ph bonds, with final...
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