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The partial oxidation of methane to synthesis gas has been studied in a continuous flow reactor using a Rh/α-Al2O3 catalyst under conditions as close as possible to those industrially relevant: pressures up to 800 kPa and temperatures higher than 1274 K in order to avoid the formation of carbon and to obtain high equilibrium selectivities to CO and H2. Intrinsic kinetic data were obtained when the...
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