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An understanding of the kinetics and mechanism of the electrochemical oxidation of ethanol is of considerable interest for the optimization of the direct ethanol fuel cell. In this paper, the electro-oxidation of ethanol in sodium hydroxide solution has been studied over 70:30 CuNi alloy supported binary platinum electrocatalysts. These comprised mixed deposits of Pt with Ru or Mo. The electrodepositions...
One of the key points to develop a cost-effective direct alcohol fuel cell (DAFC) is to investigate cheaper electrocatalysts for the oxidation of alcohol at the anode, allowing an increase in the current density and a decrease in the anodic overvoltage. In this respect, polycrystalline deposits of platinum and platinum-ruthenium on a CuNi (70:30) alloy support are investigated here. Electro-oxidation...
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