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The saponins of Chiococca alba are triterpene bidesmosides that contain glycidic moieties attached to the C-3 and C-28 carbon of their aglycone. We describe that their adjuvant potential increases in direct relationship to the length and hydrophilicity of the C-28 attached sugar chain which contains: arabinose–rhamnose in the CA2, arabinose–rhamnose–xylose in the CA3X; arabinose–rhamnose–apiose in...
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