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The electronic structures of MZr4(PO4)6 (M2+ = Ca2+, Sr2+) were calculated using the CASTEP and the band gaps for CaZr4(PO4)6 and SrZr4(PO4)6 can reach up to 4.30 and 4.45 eV, respectively. Eu2+ doped MZr4(PO4)6 were prepared by solid-state reaction method. The XRD patterns, luminescence, decay curves and thermal quenching properties of the samples were investigated. The Eu2+ ion can be totally incorporated...
The electronic structure of CaZr4(PO4)6 was calculated using the CASTEP code and the band gap for CaZr4(PO4)6 can reach up to 4.30eV. Ca1−xEuxZr4(PO4)6 (0.01⩽x⩽1) samples were prepared by a high temperature solid-state reaction method. XRD analysis shows that Eu2+ ion can be totally incorporated into CaZr4(PO4)6 forming complete solid solutions with trigonal lattice. Ca1−xEuxZr4(PO4)6 (0.01⩽x⩽1)...
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