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The Pd(OAc)2/Ti—Al-HMS/CH3OH catalyst system showed 61.2% selectivity for PO at 42.8% propylene conversion for the oxidation of propylene with molecular oxygen in an autoclave reactor at 373 K for 4 h. The catalyst is reusable using the filtration method or the vacuum distillation method after reaction. It is likely that a Ti cyclic peracid-like intermediate was formed in the system made up of a Ti...
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