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Herein, a simple aza‐aromatic compound dibenzo[a,c]phenazine (DPPZ), which exhibits single‐molecule white light with a ternary emission, consisting of simultaneous fluorescence (S1→S0) and dual room‐temperature phosphorescence (RTP, T2→S0 and T1→S0) is reported. The Commission Internationale de l' Éclairage coordinates of DPPZ powder are (0.28, 0.33). To everyone's knowledge, this is the first case...
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