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A Ag(I)‐catalyzed annulation of 1‐aminobutadiynes with anilines was described. By tuning the steric and electronic properties of anilines, 2‐aminoquinoline scaffold was constructed instead of the literature‐reported 2‐amidopyrroles. Notedly, the reactions of polyaromatic amines also proceed smoothly to afford nitrogen‐containing polyaromatics.
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