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Ammoxidation of 2,6-dichlorotoluene to 2,6-dichlorobenzonitrile is indeed an industrially important reaction for producing various commercially useful chemicals. In this contribution, differences in the catalytic performance of bulk, supported and promoted VPO samples are described. The choice of P/V ratio is found to play a key role on the catalytic properties of the catalysts. Activity is observed...
The kinetics of the vapour-phase ammoxidation of 2,6-dichlorotoluene (DCT) to 2,6-dichlorobenzonitrile (DCBN) over a vanadium phosphorus oxide (VPO) catalyst was investigated. In this paper, the main focus is on developing a mathematical model to describe the reaction kinetics of ammoxidation of DCT in a nonisothermal fixed-bed lab-scale reactor. The effect on catalytic performance of various operating...
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