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The microstructure of epitaxial CuInS2, CuGaSe2 and polycrystalline CuInS2 films was studied by transmission electron microscopy. We found that the vapour-phase epitaxy of CuInS2 below the transition temperature Tc results in films with chalcopyrite and CuAu-like structures. The formation of CuAu-like ordered phases within the films is independent of the substrate orientation, whereas the amount of...
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