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The crystals of 2,3-dicyanonaphthalene (2,3-DCN) have been obtained by a sublimation method. 2,3-DCN crystallizes in the acentric space group of the triclinic system with two independent molecules in the unit cell. The bond distances in both the independent 2,3-DCN molecules between the naphthalene nucleus fall into two groups and indicate that in the fused ring the π-electrons are not fully delocalized...
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