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The synthesis of hexagonally ordered poly(p-phenylene vinylene) (PPV) nanocomposites using polymerizable lyotropic liquid crystals (LLCs) is described. LLC monomers are used to form an inverted hexagonal phase in the presence of an aqueous PPV precursor solution. Subsequent photopolymerization to lock-in the matrix architecture, followed by thermal conversion of the precursor to PPV in the channels,...
The mixed effect of tetrasulfonated gallium phthalocyanine (GaTsPc) and tetrasulfonated zinc porphyrin (ZnTsPP) on the photoelectric conversion is reported. For the liquid junction solar cell based on the cosensitized TiO 2 electrode, cosensitization greatly enhances the photocurrent response at the longer wavelength (the GaTsPc Q band) and markedly decreases the photocurrent response in the...
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