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Tin tripod: Starting from 1,2‐distanna‐closo‐dodecaborate and tin(II) chloride, the first tripodal tin ligand was prepared. It is made up of three clusters and one central tin atom that build a frame of seven tin atoms. The coordination ability is illustrated by reaction with [Cu(CH3CN)4]PF6: a binuclear copper complex is formed surrounded by two Sn7 ligands (see picture).
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