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Hilfe von außen: Für das Kettenwachstum bei der Olefinpolymerisation an [{PO}PdR]‐Katalysatoren wird eine unimolekulare Isomerisierung von cis‐P,R‐ zu trans‐P,R‐[{PO}PdR(Olefin)] mit anschließender Insertion angenommen. Studien mit [{PO}Pd(py)2]+ (py=Pyridin) und cis/trans‐Nichtgleichgewichtsmischungen von [{PO}PdClP(O‐o‐Tolyl)3] deuten an, dass für die cis/trans‐Isomerisierung der {PO}Pd‐Komplexe...
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