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Palladium tanzt: Lineare Anilide werden in einer palladiumkatalysierten Dominosequenz aus Carbopalladierung und 1,4‐Palladium‐Verschiebung in guten bis hervorragenden Ausbeuten in die Titelverbindungen umgewandelt. Die chemoselektive C(sp3)‐H‐Aktivierung in Gegenwart konkurrierender C(sp2)‐H‐Bindungen erfolgt über einen siebengliedrigen Palladacyclus. DMA=N,N‐Dimethylacetamid, OPiv=Pivalat.
Mit Heck schnell ans Ziel: Die palladiumkatalysierte Aktivierung einer C(sp3)‐H‐Bindung durch einen in situ gebildeten σ‐Alkyl‐Palladium(II)‐Komplex ermöglicht einen neuartigen Dominoprozess aus Carbopalladierung und C(sp3)‐C(sp3)‐Verknüpfung, der rasch zu biologisch relevanten Spirooxindolen führt.
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