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Crown phosphonate 1 as a ditopic receptor-based carrier compound showed efficient dopamine transport through organic liquid membranes. A combination of extraction, transport, 1 H NMR, and mass spectral data strongly suggests that the transport complex in a chloroform phase is about 2:1 mixture of the cyclic, 1:1 complex 6 and 2:1 complex 8.
We developed a self-organized monomeric molecular container 3 based on two pairs of intramolecular hydrogen bonds between adjacent carboxylic acid moieties on the upper rim of the cavitand 1. The formation of the molecular container was confirmed by inclusion phenomena of Li + in a mixture of CDCl 3 and C 6 D 6 . The lid formed by two pairs of intramolecular hydrogen...
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