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Quasiliving atom transfer radical polymerization (ATRP) of non-fluorous monomers, styrene and n-butyl acrylate, was attempted in benzotrifluoride (BTF; α,α,α-trifluorotoluene, TFT), the simplest trifluoromethylated aromatic compound, as an alternative solvent to widely used polymerization media in ATRP and other radical polymerizations, such as benzene, toluene, xylene, diphenylether etc., with toxic,...
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