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Using broadband UV–vis femtosecond transient absorption and fluorescence up-conversion, we investigate the interaction between the haem moiety of ferric and ferrous Horse heart Cytochrome c and its single Tryptophan (Trp) residue and the energy dissipation mechanisms upon excitation at various wavelengths in the visible and the UV. Varying the amount of energy deposited in the haem does not affect...
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