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The synthesis and functional analysis of KL001 derivatives, which are modulators of the mammalian circadian clock, are described. By using cutting‐edge CH activation chemistry, a focused library of KL001 derivatives was rapidly constructed, which enabled the identification of the critical sites on KL001 derivatives that induce a rhythm‐changing activity along with the components that trigger opposite...
Eine fokussierte Bibliothek von KL001‐Derivaten, einem Periode‐verlängernden Modulator des Schlafrhythmus, wurde mittels C‐H‐Aktivierung erhalten. In ihrer Zuschrift auf S. 7299 ff. beschreiben S. Irle, T. Yoshimura, K. Itami et al. neue Periode‐verlängernde Moleküle und die ersten Periode‐verkürzenden Moleküle, die das Cryptochrom ansteuern. Das Titelbild (Haruko Hirukawa) illustriert die Fähigkeit...
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