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A class of two‐dimensional (2D) covalent organometallic polymers, with nanometer‐scale crosslinking, was obtained by arene(ruthenium) sulfur chemistry. Their ambivalent nature, with positively charged crosslinks and lypophylic branches is the key to the often sought‐for and usually hard‐to‐achieve solubility of 2D polymers in various kinds of solvents. Solubility is here controlled by the planarity...
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