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π‐Stacked dendrimers consisting of cofacially aligned donors and acceptors are developed by introducing three dendritic teracridan donors with orthogonal configuration and three triazine acceptors in periphery of hexaphenylbenzene skeleton. The dendritic structure and orthogonal configuration of teracridan not only make their outer acridan segments approaching to acceptor in close distance, but also...
Through‐space charge transfer polynorbornenes with fixed and controllable spatial alignment of donor and acceptor in edge‐to‐face/face‐to‐face stacking patterns are developed for achieving high‐efficiency blue thermally activated delayed fluorescence (TADF). The alignment is realized by using the cis, exo‐configuration of norbornene to confine donor and acceptor in close proximity, and utilizing orthogonal...
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