The Infona portal uses cookies, i.e. strings of text saved by a browser on the user's device. The portal can access those files and use them to remember the user's data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser.
The NN bond of molecular dinitrogen bridging two molybdenum atoms in the pentamethylcyclopentadienyl molybdenum complexes that bear ferrocenyldiphosphine as an auxiliary ligand is homolytically cleaved under visible light irradiation at room temperature to afford two molar molybdenum nitride complexes. Conversely, the bridging molecular dinitrogen is reformed by the oxidation of the molybdenum nitride...
Als möglicher Mechanismus der Reduktion von Wasser zu H2 wurde die reduktive Spaltung von Wasser und α‐H‐Abstraktion schon lange vermutet, bislang konnte aber kein eindeutiges Beispiel geliefert werden. Detaillierte DFT‐Rechnungen zeigen nun, dass dieser Prozess an einem MoI‐Zentrum energetisch begünstigt ist (siehe Bild). Die Bildung von H2 nach diesem Mechanismus ist auch an einem MoII‐Zentrum möglich,...
Set the date range to filter the displayed results. You can set a starting date, ending date or both. You can enter the dates manually or choose them from the calendar.