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Hydroperoxyl-alkyl-peroxyl radicals (O2QOOH) are an important radical intermediate in low-temperature combustion, and its concerted elimination reaction to produce Q″OOH and HO2 is an important reaction class in low-temperature combustion modeling of hydrocarbons. In this paper, isodesmic reaction method is used for the accurate calculation of rate constants for a representative set of 45 reactions...
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