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The larger ionic radius of Na ion (1.06Å) compared with that of Li ion (0.76Å) is a fundamental reason for the inferior diffusion kinetics of Na ion in intercalation hosts. Here we report interlayer expansion of intercalation hosts as a general strategy to facilitate the solid-state diffusion of Na ions. Based on this strategy, poly(ethylene oxide)–intercalated MoS2 composites (PEO–MoS2) were synthesized...
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