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Capillary electrophoretic separation of phenols, car☐ylic acids, and alcohols has been studied in acetonitrile. Under the condition where these compounds are not dissociated, they interact with an inorganic anion added to a running solution to form heteroconjugated anions, and migrate toward the anode. Though small anions with high charge densities (e.g. chloride) form more stable heteroconjugated...
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