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The adsorption of carbon monoxide onto ruthenium exchanged into NaY zeolite has been investigated by CW-EPR techniques using (13) C-enriched CO. A low spin eta (1){Ru(3cCO}(5) adduct with g = 2.065, g\\ = 1.987 and |A((99)Ru) = 1.3 mT, |A||(99)Ru) = 1.7 mT, |A_|(101 Ru) = 1.5 mT, A||(101)Ru) = 1.9 mT and |A|(13)C) = 6.0, |A|| |(13)C) = 6.8 mT has been identified. The magnetic parameters have been...
EPR along with MAS-NMR and QM spectroscopy have been used to investigate the structure and reactivity of hydroxymethyl radicals formed upon UV -irradiation of methanol adsorbed on MoOx /Si0(2) catalysts. The use of natural and 13C-enriched methanol allowed the authors to ascertain the 1 H superhyperfine and 13C hyperfine tensors. Based on the analysis of the magnetic parameters the structure of .CH2OH...
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