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The effect of H/D substitution in water and formaldehyde on the rate of electroless copper plating and either cathodic deposition or anodic dissolution of copper were studied by EQCM. The kinetic H/D isotope effect (k H /k D ) ca. 4.5 was found for H/D substitution in formaldehyde and of about 1 when H 2 O was replaced by D 2 O under open-circuit conditions, indicating...
Differential electrochemical mass spectrometry (DEMS) using a thin-layer flow-through electrochemical interface was used for simultaneous on-line studies of the dependence of mass spectra and Faradaic current on the electrode potential during electrocatalytic reduction of copper(II) ions by formaldehyde. The feasibility of the thin-layer flow-through DEMS cell for investigating electrode processes...
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