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Na-rich prussian blue analogues (PBs) with high coulombic efficiency are of fundamental and technological importance for sodium-ion batteries (SIBs). Here we report high-quality NaxFeFe(CN)6 nanocubes as cathode materials for SIBs and investigate their sodium storage mechanism. Among them, Na-rich Na1.70FeFe(CN)6 shows highly reversible electrochemical reactions, delivering a capacity as high as 120...
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