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Polychlorinated biphenyls spiked in soil can be extracted by a continuous flow supercritical fluid carbon dioxide system and converted on-line to bicyclohexyl using a polymer-stabilized palladium nanoparticle catalyst. The catalytic hydrodechlorination of 4-chlorobiphenyl to biphenyl follows a pseudo-first-order reaction kinetics. The subsequent hydrogenation of biphenyl to bicyclohexyl involves two...
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