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CO2‐Aktivierung In der Zuschrift auf S. 1304 ff. beschreiben M. A. Johnson et al. die Aktivierung von CO2 durch einen kationischen Nickel(I)‐Einkernkomplex. Der resultierende Komplex enthält ein stark gebogenes (148°), η2‐koordiniertes CO2‐Molekül.
We describe a systematic method for the preparation and spectroscopic characterization of a CO2 molecule coordinated to an activated bisphenoidal nickel(I) compound containing a tetraazamacrocyclic ligand in the gas phase. The resulting complex was then structurally characterized by using mass‐selected vibrational predissociation spectroscopy. The results indicate that a highly distorted CO2 molecule...
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