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The effect of chirality on the thermodynamic behavior, the morphological features, and the 2D lattice structures of 3-monopalmitoyl-sn-glycerol monolayers is studied. The results are based on measurements of the surface pressure-area (π-A) isotherms, Brewster angle microscopy (BAM), and Synchrotron X-ray diffraction at grazing incidence (GIXD). The π-A isotherms of the enantiomeric 3-monopalmitoyl-sn-glycerol...
Monolayers of the racemate and pure enantiomers of 1-hexadecyl-glycerol were investigated by grazing incidence X-ray diffraction (GID) at 5 and 20°C on compression from 0 mN m -1 to pressures greater than 30 mN m -1 . The racemate lattice is centred-rectangular for both temperatures at all investigated pressures. However, at both temperatures, there is a sharp phase transition...
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